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In
order to make the best possible decision about which type of
SODIUM CARBOXYMETHYL CELLULOSE (Gelycel) accommodates itself to
the necessities of the customer , one should take into account
factors like the type of agitation or mixing system available
(in order to define particle size in the dispersion ) ,
stability of the product (to define its DS) , the final
application of the product (to know what purity it should have
or which DS is the most indicated) , function of the product
as a binder ,thickener or colloid protector in the system (to
establish its viscosity ), etc. One of the factors to be
considered in the application of Gelycel is its viscosity . Due to
the fact that Gelycel is a product with non-Newtonian flow
characteristics and a thixotropic comportment , it is very
important to take into account - when making the viscosity
measurements - the following factors : |
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Type of
viscosity meter
It is recommended to make the measurement using rotational
viscosity meters of the Brookfield type . It is necessary to
specify the type of viscosity meter used because depending on
the type of equipment used (LV, RV, etc) a different torque is
applied to the sample being measured and the spindles have
different geometry. This leads to varying values of viscosity
by doing the evaluations on different equipment (LV, RV, etc)
using the same sample .
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Spindle/RPM
Each spindle possesses its own geometry characteristic .
Additionally the geometry of the spindles used with LV
viscometers is different to the geometry of the spindles used
with the RV series . Added to this , the Gelycel is a
non-Newtonian fluid , or in other words, the viscosity value
obtained depends on the RPM used in the measurement. These
factors mean that when a viscosity measurement of Gelycel is made
, it is convenient to indicate the number of spindle used and
the speed (RPM) with which the product viscosity is evaluated
.
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Solid
contents :
The viscosity of Gelycel is directly proportional to the solids
content , which is to say, the higher the solids content of
the Gelycel, the higher the viscosity value obtained will be. This
is why it is convenient to indicate at what concentration the
viscosity measurement is made. The same reason applies to the
fact that one should indicate if the evaluation has been made
on a dry base or a wet base .
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Temperature
The viscosity is inversely proportional to the temperature,
which is to say , the higher the temperature , the lower the
viscosity measurement obtained . Our measurements are carried
out at 25ºC. If you make your measurements at temperatures
different to 25ºC we would be pleased if you could let us
know by informing our technical assistant. |
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We
will now describe in a general way , the viscosity evaluation
method that is used in our installations |
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*Calculate
the humidity in a general form.
*Weigh the quantity of Gelycel required to prepare 500 grams of
solution. For example, if you wish to prepare 500 grams of a
2% Gelycel solution and the humidity of the CMS is 5% , the
quantity of Gelycel to be weighed will be :
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Weight
Gelycel, |
g
= 2 * (500/100) |
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(100- % H) |
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100 |
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Weight
Gelycel, |
g
= 10.5263 |
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Where :
2:concentration of the solution in
percentage
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H
%: humidity of the solution in
percentage |
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*Weigh
the quantity of water necessary to obtain 500 grams of
solution. To do this you proceed in the following manner:
Weight
of water, gr= 500 – weight of Gelycel
Weight of water, ml = 489.4 gm (grams)
Note : 1 gram of water = 1 ml volume
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Place
the agitator in the water and raise to approximately 1,000
rpm. |
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Slowly add
the sample to the formed vortex . This addition must be
performed slowly so as to avoid agglomeration . |
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Agitate
until de Gelycel is completely dissolved |
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Adjust the
temperature to 25ºC. |
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Simultaneously
choose the spindle and the RPM with which you wish to fulfil
the evaluation . |
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Pour the
recently prepared solution of Gelycel into a conical cup. |
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Leave the
solution to settle for a minute , then place the spindle into
the solution up to the meniscus marked on the spindle |
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Start
the viscometer and rotate for one minute |
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Take
the viscosity reading after one minute of rotation |
The
spindles and RPM we use for our evaluations are as follows:
VISCOSITY METER LVF |
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Viscosity
Range, Cps. |
Spindle
No. |
RPM |
Factor |
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100
Maximum |
1 |
60 |
1 |
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100
– 200 |
1 |
30 |
2 |
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200
– 1000 |
2 |
30 |
10 |
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1000
– 4000 |
3 |
30 |
40 |
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4000
– 20000 |
4 |
30 |
200 |
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20000
– 50000 |
4 |
12 |
500 |
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50000
– 100000 |
4 |
6 |
1000 |
| The
evaluations are made using a Brookfield LVF viscometer , dry
base , at 25ºC. |
| Should
you have any doubts , do not hesitate to contact our technical
assistant. |
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